Posebna izdanja (Srpdka kraljevska akademija), Том 237 |
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Страница 15
... Carbonyl groups are readily reduced by means of lithium aluminum hydride yielding hydroxy compounds ; 3 , 81-124 ... group , are readily reduced by lithium aluminum hydride to the corresponding alcohols . 81 , 82 125-133 , 1062 , 1067 , 1084 ...
... Carbonyl groups are readily reduced by means of lithium aluminum hydride yielding hydroxy compounds ; 3 , 81-124 ... group , are readily reduced by lithium aluminum hydride to the corresponding alcohols . 81 , 82 125-133 , 1062 , 1067 , 1084 ...
Страница 17
... CARBONYL GROUP The carbonyl group in certain aromatic aldehydes and ketones containing amino or methoxy groups ortho or para to the oxygen function , when reduced under forcing conditions ( excess lithium aluminum hydride , heating for ...
... CARBONYL GROUP The carbonyl group in certain aromatic aldehydes and ketones containing amino or methoxy groups ortho or para to the oxygen function , when reduced under forcing conditions ( excess lithium aluminum hydride , heating for ...
Страница 25
... carbonyl function , namely a - methyl ketones , are formed as the result of hydro- genolysis of the hydroxymethylene group . 1878 , 1413 Reductones , i . e . compounds containing the enediol- ( a ) -a - carbonyl function ( XLIX ) , as ...
... carbonyl function , namely a - methyl ketones , are formed as the result of hydro- genolysis of the hydroxymethylene group . 1878 , 1413 Reductones , i . e . compounds containing the enediol- ( a ) -a - carbonyl function ( XLIX ) , as ...
Садржај
LITHIUM ALUMINUM HYDRIDE AS A REDUCING AGENT IN | 1 |
III | 7 |
Special Procedures and Preparation of Hydride Solutions | 13 |
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Acta action of lithium alcohols aldehydes aliphatic alkyl amides amino aromatic attack by lithium carbon atom carbonyl carbonyl group CH₂ CH₂O CH₂OH CH3 CH3 Chem Chemistry and Industry Chim chloride complex compounds containing converted corresponding cyclic derivatives diethyl ether dihydro diol double bond enol epoxides ester group ether solution ethylenic forcing conditions formation functional groups furnishes give H₂C H₂CO H₂O halides halogen Helv heterocyclic Hydride in Organic hydrocarbons hydrogen hydrogenolysis hydrolysis hydroxy hydroxyl group intermediate Karrer ketones lactams lactone LIAIHA lithium aluminum hydride lithium hydride means of lithium mechanism methyl mixture Monatsh nitriles nitro nitrogen nucleophilic obtained olefin optically active oxazolone oxide polar racemic react with lithium reaction reagent reducing agent reductions by lithium ring Rosenkranz saturated solvent steroids sulfinic acids sulfonate sulfonic acids temperatures tertiary tetrahydrofuran unsaturated VIII XVII XVIII XXIII yields