Posebna izdanja (Srpdka kraljevska akademija), Том 237 |
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Страница 10
... enol form , whereas in reactions with lithium aluminum hydride a state of equi- librium is reached ( probably displaced to a certain extent in the di- rection of the enol tautomer ) . It appears that the hydride reacts rapidly with both ...
... enol form , whereas in reactions with lithium aluminum hydride a state of equi- librium is reached ( probably displaced to a certain extent in the di- rection of the enol tautomer ) . It appears that the hydride reacts rapidly with both ...
Страница 42
... ENOL ESTERS Enol esters of cyclic ketones react with lithium aluminum hydride to produce a mixture of the epimeric hydroxy compounds and star- ting ketone , the double bond being reduced in the course of the reaction.20 , 21 , 564-566 ...
... ENOL ESTERS Enol esters of cyclic ketones react with lithium aluminum hydride to produce a mixture of the epimeric hydroxy compounds and star- ting ketone , the double bond being reduced in the course of the reaction.20 , 21 , 564-566 ...
Страница 80
... enol ethers , 257 , 258 , 261 , 725 , 726 , 923 , 931 , 1115 , 1258 , 1299 , 1375 , 1473 thio - enol ethers , 247 , 283 , 1508 acetals , 721 , 724 , 1083 , 1239 , 1241 , 1392 cyclic hemiacetals ( with methylated hydroxyl groups ) , 185 ...
... enol ethers , 257 , 258 , 261 , 725 , 726 , 923 , 931 , 1115 , 1258 , 1299 , 1375 , 1473 thio - enol ethers , 247 , 283 , 1508 acetals , 721 , 724 , 1083 , 1239 , 1241 , 1392 cyclic hemiacetals ( with methylated hydroxyl groups ) , 185 ...
Садржај
LITHIUM ALUMINUM HYDRIDE AS A REDUCING AGENT IN | 1 |
III | 7 |
Special Procedures and Preparation of Hydride Solutions | 13 |
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Acta action of lithium alcohols aldehydes aliphatic alkyl amides amino aromatic attack by lithium carbon atom carbonyl carbonyl group CH₂ CH₂O CH₂OH CH3 CH3 Chem Chemistry and Industry Chim chloride complex compounds containing converted corresponding cyclic derivatives diethyl ether dihydro diol double bond enol epoxides ester group ether solution ethylenic forcing conditions formation functional groups furnishes give H₂C H₂CO H₂O halides halogen Helv heterocyclic Hydride in Organic hydrocarbons hydrogen hydrogenolysis hydrolysis hydroxy hydroxyl group intermediate Karrer ketones lactams lactone LIAIHA lithium aluminum hydride lithium hydride means of lithium mechanism methyl mixture Monatsh nitriles nitro nitrogen nucleophilic obtained olefin optically active oxazolone oxide polar racemic react with lithium reaction reagent reducing agent reductions by lithium ring Rosenkranz saturated solvent steroids sulfinic acids sulfonate sulfonic acids temperatures tertiary tetrahydrofuran unsaturated VIII XVII XVIII XXIII yields